Phase behaviour of colloids in confining geometry
نویسندگان
چکیده
We review recent experimental and theoretical studies on two-dimensional (2D) melting in the presence of a one-dimensional (1D) periodic potential. It is demonstrated that a colloidal suspension which is exposed to the interference pattern of two overlapping laser beams show a phase behaviour being totally different from that of 2D systems on homogeneous substrates. This is attributed to the role of particle fluctuations which in the presence of sufficiently strong periodic external potentials enhance particle interactions and thus promote crystallization.
منابع مشابه
Optical Limiting Properties of Colloids Enhanced by Gold Nanoparticles Based on Nonlinear Refraction for Cw Laser Illumination
In this work, thermo-optical properties of gold nanoparticle colloids are studied using continuous wave (CW) laser irradiation at 532 nm. The nanoparticle colloids are fabricated by 18 ns pulsed laser ablation of pure gold plate in the distilled water. The formation of the nanoparticles has been evidenced by optical absorption spectra and transmission electron microscopy. The nonlinear optical ...
متن کاملSedimentation of a two-dimensional colloidal mixture exhibiting liquid-liquid and gas-liquid phase separation: a dynamical density functional theory study.
We present dynamical density functional theory results for the time evolution of the density distribution of a sedimenting model two-dimensional binary mixture of colloids. The interplay between the bulk phase behaviour of the mixture, its interfacial properties at the confining walls, and the gravitational field gives rise to a rich variety of equilibrium and non-equilibrium morphologies. In t...
متن کاملMicrofluidic assembly of homogeneous and Janus colloid-filled hydrogel granules.
The microfluidic assembly of colloid-filled hydrogel granules of varying shape and composition is described. First, drops are formed by shearing a concentrated colloidal microsphere-acrylamide suspension in a continuous oil phase using a sheath-flow device. Both homogeneous and Janus (hemispherically distinct) spheres and disks are produced by confining the assembled drops in microchannels of v...
متن کاملFrom capillary condensation to interface localization transitions in colloid-polymer mixtures confined in thin-film geometry.
Monte Carlo simulations of the Asakura-Oosawa model for colloid-polymer mixtures confined between two parallel repulsive structureless walls are presented and analyzed in the light of current theories on capillary condensation and interface localization transitions. Choosing a polymer-to-colloid size ratio of q=0.8 and studying ultrathin films in the range of D=3 to D=10 colloid diameters thick...
متن کاملInternal structure and swelling behaviour of in silico microgel particles.
Microgels are soft colloids that, by virtue of their polymeric nature, can react to external stimuli such as temperature or pH by changing their size. The resulting swelling/deswelling transition can be exploited in fundamental research as well as for many diverse practical applications, ranging from art restoration to medicine. Such an extraordinary versatility stems from the complex internal ...
متن کامل